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However, for millennia fire was seen simply as a mystical force that could transform one substance into another (burning wood, or boiling water) while producing heat and light. ДЄrguably the first chemical reaction used in a controlled manner was fire. Egyptian weapons made from meteoric iron in about 3000 BC were highly prized as 'daggers from Heaven'. Silver, copper, tin and meteoric iron can also be found native, allowing a limited amount of metalworking in ancient cultures. Small amounts of natural gold have been found in Spanish caves used during the late Paleolithic period, around 40,000 BC.

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The earliest recorded metal employed by humans seems to be gold, which can be found free or 'native'. Main articles: Ferrous metallurgy and History of metallurgy in the Indian subcontinent Paintings drawn by early humans consisting of early humans mixing animal blood with other liquids found on cave walls also indicate a small knowledge of chemistry. It indicates that early humans had an elementary knowledge of chemistry.

4.9.1 Ramsay's discovery of the noble gasesДЄncient history Early humans ДЄ 100,000-year-old ochre-processing workshop was found at Blombos Cave in South Africa.3.2 Development and dismantling of phlogiston.3 17th and 18th centuries: Early chemistry.The history of chemistry is intertwined with the history of thermodynamics, especially through the work of Willard Gibbs. While both alchemy and chemistry are concerned with matter and its transformations, chemists are seen as applying scientific method to their work. The distinction began to emerge when a clear differentiation was made between chemistry and alchemy by Robert Boyle in his work The Sceptical Chymist (1661). However, by performing experiments and recording the results, alchemists set the stage for modern chemistry. The protoscience of chemistry, alchemy, was unsuccessful in explaining the nature of matter and its transformations. Examples include the discovery of fire, extracting metals from ores, making pottery and glazes, fermenting beer and wine, extracting chemicals from plants for medicine and perfume, rendering fat into soap, making glass, By 1000 BC, civilizations used technologies that would eventually form the basis of the various branches of chemistry. The history of chemistry represents a time span from ancient history to the present. The periodic table is one of the most potent icons in science, lying at the core of chemistry and embodying the most fundamental principles of the field. The 1871 periodic table constructed by Dmitri Mendeleev.

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